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Article Dans Une Revue Physical Review B Année : 2017

A theoretical approach for elastically driven cooperative switching of spin crossover compounds impacted by an ultrashot laser pulse

Cristian Enachescu
Seiji Miyashita
Roman Stancu
  • Fonction : Auteur
Maciej Lorenc
Roman Bertoni
Hervé Cailleau
Eric Collet

Résumé

In this paper we use an elastic model in order to study the elastically driven cooperative switching of spin crossover materials after femtosecond laser excitation. In this model, the molecules occupy a triangular lattice in open boundaries systems and are connected by springs. The volume change of a molecule between its two possible spin states, low-spin and high-spin, determines a variation of the spring length and therefore induces elastic interactions between molecules, which propagates throughout the whole sample as elastic distortions. This model is able to reproduce the multi-step out-of-equilibrium response to ultrashort laser excitation and especially the elastically-driven cooperative response. Then this model is developed in order to predict the behaviour of the system as a function of its different physical parameters, such as the magnitude of the elastic constant or the homogeneity of the photoexcitation. The contribution of the reorganisation of the molecular states during elastic steps, leading to clusters of high-spin molecules towards edge or corners is also revealed.
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Dates et versions

hal-01552083 , version 1 (30-06-2017)

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Cristian Enachescu, Roman Stoleriu, Masamichi Nishino, Seiji Miyashita, Roman Stancu, et al.. A theoretical approach for elastically driven cooperative switching of spin crossover compounds impacted by an ultrashot laser pulse. Physical Review B, 2017, 95 (22), pp.224107. ⟨10.1103/PhysRevB.95.224107⟩. ⟨hal-01552083⟩
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