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Article Dans Une Revue Catalysis Communications Année : 2017

Hydrogenation of ketones with a manganese PN3P pincer pre-catalyst

Résumé

A catalytic hydrogenation of carbonyl derivs. with a manganese pre-catalyst has been developed. The key feature is the use of an air stable cationic manganese pre-catalyst bearing a tridendate ligand with a 2,6-(diaminopyridinyl)diphosphine scaffold. Under 50 bar of H2, at 130°, various ketones were reduced to the corresponding alcs. with moderate to good yield.

Domaines

Chimie
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Dates et versions

hal-01475820 , version 1 (24-02-2017)

Identifiants

Citer

Antoine Bruneau-Voisine, Ding Wang, Thierry Roisnel, Christophe Darcel, Jean-Baptiste Sortais. Hydrogenation of ketones with a manganese PN3P pincer pre-catalyst. Catalysis Communications, 2017, 92, pp.1-4. ⟨10.1016/j.catcom.2016.12.017⟩. ⟨hal-01475820⟩
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