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Journal Articles Chemical Communications Year : 2001

New paramagnetic ruthenium complexes via one-electron reduction of metallacumulenes

Stéphane Rigaut
O Maury
D Touchard
  • Function : Author

Abstract

One-electron reductions of [Cl(dppe)(2)Ru=C=C=CR2]PF6 (R = Ph, Me) and [Cl(dppe)(2)Ru=C=C=C=C=CPh2]PF6 with Co(C5H5)(2) provide radical species with the unpaired electron localized on the trisubstituted carbon atom of the cumulene moiety as shown by hydrogen atom capture and EPR spectroscopy.
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hal-01475066 , version 1 (23-02-2017)

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Stéphane Rigaut, O Maury, D Touchard, Ph Dixneuf. New paramagnetic ruthenium complexes via one-electron reduction of metallacumulenes. Chemical Communications, 2001, 4, pp.373--374. ⟨10.1039/b008893p⟩. ⟨hal-01475066⟩
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