%0 Journal Article %T Grafting cyclams or related compounds over a porphyrin %+ Laboratoire Innovation en Chimie des Surfaces et NanoSciences (LICSEN) %A Boitrel, Bernard %A Bruno, Andrioletti %A Guilard, Roger %< avec comité de lecture %J Comptes rendus de l’Académie des sciences. Série 2 %I Gauthier-Villars %V 323 %N 12 %P 859-864 %8 1996 %D 1996 %Z Chemical SciencesJournal articles %X The synthesis and characterization of several new polymacrocycles containing a porphyrin and one or two cyclam units are described. The use of 1,8-ditertbutyloxycarbonyl cyclam (1,8-diBoc-cyclam) led to new biomimetic models in good yields. In order to tune the distance between the macrocycles, two different linkers were successively used. Such a method might promote a bimetallic interaction between the two corresponding complexes. %G English %L hal-01469675 %U https://univ-rennes.hal.science/hal-01469675 %~ CEA %~ CNRS %~ PUBNIMBE %~ INC-CNRS %~ IRAMIS-NIMBE %~ TEST-UNIV-RENNES %~ UNIV-RENNES %~ IRAMIS %~ GS-PHYSIQUE %~ TEST2-HALCNRS