%0 Journal Article %T Tripodal and/or picket porphyrins to mimic the cytochrome c oxidase activity %+ Institut des Sciences Chimiques de Rennes (ISCR) %+ Chimie, Electrochimie Moléculaires et Chimie Analytique (CEMCA) %A Boitrel, Bernard %A Didier, Amandine %A Ricard, David %A L'Her, Maurice %< avec comité de lecture %@ 1088-4246 %J Journal of Porphyrins and Phthalocyanines %I World Scientific Publishing %V 7 %N 4-5 %P 282-290 %8 2003 %D 2003 %Z Chemical SciencesJournal articles %X The efficiency of different series of tris-(2-aminoethyl)amine TREN-capped porphyrins as catalysts for the electroreduction of dioxygen has been studied after adsorption of the molecules at the surface of a graphite electrode. The influence of two structural features have been explored:the relative position of the two metals in the iron-copper bimetallic complexes and the nature of thebenzyl groups of the tripod itself. These compounds have also been compared with picket porphyrinsbearing aromatic amino functions, e.g. quinoline. The conclusions obtained in the case of TRENcappedcatalysts cannot be extended to those bearing aromatic pickets. %G English %L hal-01469393 %U https://univ-rennes.hal.science/hal-01469393 %~ UNIV-BREST %~ UNIV-RENNES1 %~ CNRS %~ INSA-RENNES %~ ENSC-RENNES %~ ISCR %~ SCR_OMC2012 %~ ISCR-OMC %~ UR1-SPM %~ INC-CNRS %~ UR1-UFR-SPM %~ UR1-HAL %~ UR1-SDLM %~ CEMCA-BREST %~ TEST-UNIV-RENNES %~ TEST-UR-CSS %~ UNIV-RENNES %~ INSA-GROUPE %~ IBSAM %~ UR1-MMS %~ TEST2-HALCNRS