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Communication Dans Un Congrès Année : 2016

Low energy phonon spectroscopy and translation-rotation coupling in hybrid perovskites crystals

Résumé

Despite the wealth of research conducted the last three years on hybrid organic perovskites (HOP), several questions remain open including: to what extend the organic moiety changes the properties of the material as compared to all-inorganic (AIP) related perovskite structures. To ultimately reach an answer to this question, we have recently introduced two approaches that were designed to take the stochastic molecular degrees of freedom into account, and suggested that the high temperature cubic phase of HOP and AIP is an appropriate reference phase to rationalize HOP's properties. In this paper, we recall the main concepts and show recent molecular dynamic results (figure 1) to discuss more specifically the various possible couplings between charge carriers and low energy excitations such as acoustic and optical phonons. As available experimental or simulated data on low energy excitations are limited, we also present preliminary neutron and Brillouin scattering, as well as ultrasonic measurements obtained on freshly prepared single crystals of CH 3 NH 3 PbBr 3.
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Dates et versions

hal-01416169 , version 1 (26-01-2017)

Identifiants

  • HAL Id : hal-01416169 , version 1

Citer

Antoine Létoublon, Serge Paofai, Philippe Bourges, Stéphane Cordier, Olivier Durand, et al.. Low energy phonon spectroscopy and translation-rotation coupling in hybrid perovskites crystals. 2è Journées Pérovskites Hybrides (JPH 2016), May 2016, Rennes, France. ⟨hal-01416169⟩
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