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Article Dans Une Revue Chemistry - A European Journal Année : 2015

A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics

Résumé

A simple synthetic method allows the one-pot assembly of C-3-symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first examples of stable triangular all-metal heteroaromatics. In contrast to traditional heteroaromatic molecules formed combining main-group elements, they actually retain structural and electronic features of their homonuclear analogues.

Domaines

Chimie organique
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Dates et versions

hal-01397969 , version 1 (16-11-2016)

Identifiants

Citer

Yanlan Wang, Pierre-Alexandre Deyris, Tatiana Caneque, Florent Blanchard, Yanling Li, et al.. A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics. Chemistry - A European Journal, 2015, 21 (35), pp.12271-12274. ⟨10.1002/chem.201501239⟩. ⟨hal-01397969⟩
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