%0 Journal Article %T Amine synthesis via transition metal homogeneous catalysed hydrosilylation %+ Institut des Sciences Chimiques de Rennes (ISCR) %A Li, Bin %A Sortais, Jean-Baptiste %A Darcel, Christophe %Z University of Rennes 1 %Z CNRS %Z Science Foundation for Young Teachers of Wuyi University [2014zk04] %Z Natural Science Foundation of Guangdong Province [2014A030310211] %Z Foundation of Department of Education of Guangdong Province [2014KQNCX156] %< avec comité de lecture %@ 2046-2069 %J RSC Advances %I Royal Society of Chemistry %V 6 %N 62 %P S7603--S7625 %8 2016 %D 2016 %R 10.1039/c6ra10494k %K direct reductive amination %K nickel hydride complex %K one-pot conversion %K asymmetric hydrosilylation %K enantioselective hydrosilylation %K selective reduction %K secondary amides %K tertiary amides %K transfer hydrogenation %K titanium complexes %Z Chemical SciencesJournal articles %X Amines are among the most important compounds due to their wide applications in several areas of importance. Among the numerous synthetic methodologies, this review provides a comprehensive summary of the preparation of amines involving homogeneous transition metal catalysed hydrosilylation methodologies including the reduction of imine, amide, nitro and nitrile derivatives. In addition, challenging tandem reactions such as reductive amination or the use of CO2 as a C-1-building block in N-methylation of amines will also be discussed. %G English %L hal-01357397 %U https://univ-rennes.hal.science/hal-01357397 %~ UNIV-RENNES1 %~ CNRS %~ INSA-RENNES %~ ENSC-RENNES %~ ISCR %~ SCR_OMC2012 %~ ISCR-OMC %~ STATS-UR1 %~ UR1-SPM %~ INC-CNRS %~ UR1-UFR-SPM %~ UR1-HAL %~ UR1-SDLM %~ TEST-UNIV-RENNES %~ TEST-UR-CSS %~ UNIV-RENNES %~ INSA-GROUPE %~ UR1-MMS %~ TEST2-HALCNRS