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Journal Articles ACS Applied Materials & Interfaces Year : 2016

Reversible Luminescence Modulation upon an Electric Field on a Full Solid-State Device Based on Lanthanide Dimers

Abstract

Switching luminescence of lanthanide-based molecules through an external electric field is considered as a promising approach toward novel functional molecule-based devices. Classic routes use casted films and liquid electrolyte as media for redox reactions. Such protocol, even if efficient, is relatively hard to turn into an effective solid-state device. In this work, we explicitly synthesize lanthanide-based dimers whose luminescent behavior is affected by the presence of Cu(2+) ions. Excellent evaporability of the dimers and utilization of Cu(2+)-based solid-state electrolyte makes it possible to reproduce solution behavior at the solid state. Reversible modulation of Cu(2+) ions transport can be achieved by an electric field in a solid-state device, where lanthanide-related luminescence is driven by an electric field. These findings provide a proof-of-concept alternative approach for electrically driven modulation of solid-state luminescence and show promising potential for information storage media in the future
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Dates and versions

hal-01338528 , version 1 (28-06-2016)

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Xiaohui Yi, Jie Shang, Liang Pan, Hongwei Tan, Bin Chen, et al.. Reversible Luminescence Modulation upon an Electric Field on a Full Solid-State Device Based on Lanthanide Dimers. ACS Applied Materials & Interfaces, 2016, 8 (24), pp.15551--15556. ⟨10.1021/acsami.6b04451⟩. ⟨hal-01338528⟩
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