Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn(2+) binding - Université de Rennes Access content directly
Journal Articles Chemical Communications Year : 2016

Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn(2+) binding

Abstract

The molecular conformation of a bis-helicenic terpyridine system is strongly modified upon binding to Zn(ii) ion, a process that is accompanied by large changes in the optical and chiroptical properties. This system affords a new type of helicene-based chiroptical switching.[on SciFinder (R)]
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Dates and versions

hal-01301464 , version 1 (02-06-2016)

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Helena Isla, Monika Srebro-Hooper, Marion Jean, Nicolas Vanthuyne, Thierry Roisnel, et al.. Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn(2+) binding. Chemical Communications, 2016, 52 (35), pp.5932-5935. ⟨10.1039/C6CC01748G⟩. ⟨hal-01301464⟩
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