%0 Journal Article %T Synthesis and chemical reactivity of new zinc porphyrin diazoacetates catalyzed by ruthenium and iron porphyrins %+ Institut des Sciences Chimiques de Rennes (ISCR) %A Carrié, Daniel %A Srour, Hassan %A Le Maux, Paul %A Simonneaux, Gérard %< avec comité de lecture %@ 0040-4039 %J Tetrahedron Letters %I Elsevier %V 57 %N 10 %P 1179–1182 %8 2016 %D 2016 %R 10.1016/j.tetlet.2016.02.010 %K Ruthenium porphyrin %K Meso-phenyl-diazo-porphyrin ester %K Catalytic carbene transfer %K iron porphyrin %Z Life Sciences [q-bio]/Pharmaceutical sciences %Z Chemical SciencesJournal articles %X Zinc porphyrin diazoacetates were synthesized from the corresponding bromoacetates by treatment with N,N’-ditosylhydrazine in ∼70% yield. The transfer of carbenoids derived from the porphyrin diazo compounds catalyzed by metalloporphyrins (Ru,Fe) undergoes dimerization, cyclopropanation, N-H and S-H insertion reactions, respectively %G English %2 https://univ-rennes.hal.science/hal-01269738/document %2 https://univ-rennes.hal.science/hal-01269738/file/Synthesis%20and%20chemical%20reactivity%20of%20new%20zinc.pdf %L hal-01269738 %U https://univ-rennes.hal.science/hal-01269738 %~ UNIV-RENNES1 %~ CNRS %~ INSA-RENNES %~ ENSC-RENNES %~ ISCR %~ SCR_ICMV %~ STATS-UR1 %~ UR1-SPM %~ INC-CNRS %~ UR1-UFR-SPM %~ UR1-HAL %~ ISCR-CORINT %~ UR1-SDLM %~ TEST-UNIV-RENNES %~ TEST-UR-CSS %~ UNIV-RENNES %~ INSA-GROUPE %~ ISCR-CORINT1 %~ UR1-MMS %~ TEST2-HALCNRS