Synthesis of a BEDT-TTF bipyridine organic donor and the first FeII coordination complex with a redox-active ligand. - Université de Rennes Accéder directement au contenu
Article Dans Une Revue European Journal of Inorganic Chemistry Année : 2006

Synthesis of a BEDT-TTF bipyridine organic donor and the first FeII coordination complex with a redox-active ligand.

Résumé

The synthesis of the new ligand, BEDT-TTF-bpy [4,5-ethylenedithio-4',5'-(4'-methyl-2,2'-dipyrid-4- ylethylenedithio)-tetrathiafulvalene] is reported. The first FeII coordination complex, namely [Fe(NCS)2(BEDT-TTF-bpy)2], with this redox-active ligand is obtained. Magnetic measurements and Mossbauer spectroscopy revealed the coexistence of high-spin and low-spin FeII species with a ratio of 40:60 in this compd. The complex also was studied using cyclic voltammetry.

Dates et versions

hal-01151571 , version 1 (13-05-2015)

Identifiants

Citer

Katel Hervé, Shi-Xia Liu, Olivier Cador, Stéphane Golhen, Yann Le Gal, et al.. Synthesis of a BEDT-TTF bipyridine organic donor and the first FeII coordination complex with a redox-active ligand.. European Journal of Inorganic Chemistry, 2006, pp.3498--3502. ⟨10.1002/ejic.200600351⟩. ⟨hal-01151571⟩
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