Catalytic, highly enantioselective, direct amination of enecarbamates. - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2015

Catalytic, highly enantioselective, direct amination of enecarbamates.

Résumé

Amination of enecarbamates with dibenzylazodicarboxylate and oxygenated nucleophiles in the presence of a catalytic amount of chiral phosphoric acid afforded optically active stable precursors of α-hydrazinoimines, which were reduced or oxidized, respectively, to vicinal diamines or α-amino acid precursors with excellent yield and enantioselectivity.

Domaines

Chimie
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Dates et versions

hal-01138300 , version 1 (01-04-2015)

Identifiants

Citer

Audrey Dumoulin, Claudia Lalli, Pascal Retailleau, Géraldine Masson. Catalytic, highly enantioselective, direct amination of enecarbamates.. Chemical Communications, 2015, 51 (25), pp.5383-5386. ⟨10.1039/C4CC08052A⟩. ⟨hal-01138300⟩
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