Experimental and theoretical evidence that electrostatics governs easy-axis orientation in DyIII-based molecular chains - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2014

Experimental and theoretical evidence that electrostatics governs easy-axis orientation in DyIII-based molecular chains

Résumé

Magnetic slow relaxation is observed in a DyIII-based molecular chain and the magnetic easy-axis is determined via single-crystal magnetometry. Ab initio calculations confirm its orientation and highlight that the latter is governed neither by coordination polyhedron symmetry nor by the chain direction but rather by the single-ion electrostatic environment, a feature that is confirmed by a similar theoretical analysis on other DyIII chains.
Fichier non déposé

Dates et versions

hal-01072043 , version 1 (07-10-2014)

Identifiants

Citer

Julie Jung, François Le Natur, Olivier Cador, Fabrice Pointillart, Guillaume Calvez, et al.. Experimental and theoretical evidence that electrostatics governs easy-axis orientation in DyIII-based molecular chains. Chemical Communications, 2014, 50, pp.13346-13348. ⟨10.1039/c4cc05062b⟩. ⟨hal-01072043⟩
85 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More