Partial Sublimation of Enantioenriched Amino Acids at Low Temperature. Is it Coming From the Formation of a Euatmotic Composition of the Gaseous Phase?. - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Journal of Organic Chemistry Année : 2013

Partial Sublimation of Enantioenriched Amino Acids at Low Temperature. Is it Coming From the Formation of a Euatmotic Composition of the Gaseous Phase?.

Résumé

The partial sublimation of enantioenriched amino acids was performed slowly at low temp. with the aim to det. the rules of sublimation of these compds. Although the formation of a euatmotic compn. of the gaseous phase starting from DL + L mixts. of Leu, Pro, and Phe can be deduced from the enantiomeric excess of sublimates, the behavior of the kinetic conglomerate explains the results for D + L mixts. of Ala, Leu, Val, and Pro. Consequently, the enantiomeric excess of the partial sublimate is dependent not only on the studied compd. but also on the compn. of the starting mixt. [on SciFinder(R)]

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Dates et versions

hal-01069944 , version 1 (30-09-2014)

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Arkadii V. Tarasevych, Alexander E Sorochinsky, Valery P. Kukhar, Aurelien Chollet, Richard Daniellou, et al.. Partial Sublimation of Enantioenriched Amino Acids at Low Temperature. Is it Coming From the Formation of a Euatmotic Composition of the Gaseous Phase?.. Journal of Organic Chemistry, 2013, 78, pp.10530--10533. ⟨10.1021/jo4017474⟩. ⟨hal-01069944⟩
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