Heat Attachment Method for the Immobilization of TiO2 on Glass Plates: Application to Photodegradation of Basic Yellow Dye and Optimization of Operating Parameters, Using Response Surface Methodology - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Industrial and engineering chemistry research Année : 2014

Heat Attachment Method for the Immobilization of TiO2 on Glass Plates: Application to Photodegradation of Basic Yellow Dye and Optimization of Operating Parameters, Using Response Surface Methodology

Résumé

The UV/TiO2/H2O2 degradation of Basic Yellow 28 dye (BY28) in aqueous solutions was investigated with immobilized P-25 TiO2 powder on a glass plate by a heat attachment method. A central composite design (CCD) was employed for the screening of the significant parameters (flow rate, initial dye concentration, solution pH, and initial H2O2 concentration) and to identify the most relevant interactions between the operating parameters. Results showed that solvent type and thickness of the coating are very effective on the photoactivity of immobilized TiO2. The model equation obtained led to a classification of the parameters based on their level of significance. In addition, a relevant interaction between the initial dye concentration and the initial H2O2 concentration was highlighted. After performing a screening of the various operating parameters, response surface analysis led to the optimal conditions for the yield of BY28 degradation, resulting in 96% decolorization yield.
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Dates et versions

hal-00954727 , version 1 (03-03-2014)

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Yahia Cherif, Idris Yahiaoui, Farida Aissani-Benissad, K. Madi, N. Benmehdi, et al.. Heat Attachment Method for the Immobilization of TiO2 on Glass Plates: Application to Photodegradation of Basic Yellow Dye and Optimization of Operating Parameters, Using Response Surface Methodology. Industrial and engineering chemistry research, 2014, 53 (10), pp.3813-3819. ⟨10.1021/ie403970m⟩. ⟨hal-00954727⟩
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