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Article Dans Une Revue Tetrahedron Letters Année : 2013

Synthesis and photochemical reactivity of caged glutamates with a π-​extended coumarin chromophore as a photolabile protecting group

Résumé

'Caging' and 'uncaging' bioactive substrates are key techniques in studying a wide variety of biological processes. In the present study, two-types of novel caged glutamates with a two-photon absorption (TPA) core, that is, π-extended coumarin, were synthesized and their photochemical release of glutamate was analyzed. The high yields of glutamate (>92%) were observed in the photolysis of compounds 1 and 10, respectively.
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Dates et versions

hal-00908704 , version 1 (16-01-2014)

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Yuya Sakamoto, Srikanth Boinapally, Claudine Katan, Manabu Abe. Synthesis and photochemical reactivity of caged glutamates with a π-​extended coumarin chromophore as a photolabile protecting group. Tetrahedron Letters, 2013, 54 (52), pp.7171-7174. ⟨10.1016/j.tetlet.2013.10.107⟩. ⟨hal-00908704⟩
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