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Article Dans Une Revue Current Organic Chemistry Année : 2013

About the Use of Rhodium Nanoparticles in Hydrogenation and Hydroformylation Reactions

Miguel Guerrero
  • Fonction : Auteur
Nguyet T. Chau Than
  • Fonction : Auteur
Sébastien Noël
Frédéric Hapiot
Alain Roucoux
Eric Monflier
Karine Philippot

Résumé

Even if rhodium is one of the rarest and the most costly metals, this noble metal has found many catalytic applications, particularly in hydrogenation and hydroformylation reactions owing to its specific catalytic properties. Tremendous research activities are thus carried out by the scientific community for the development of novel rhodium-based catalysts. This interest for rhodium catalysts concerns also the modern "nanocatalysis" area, situated at the frontier between heterogeneous and homogeneous ones, nanoparticles soluble in a liquid phase being considered as "pseudo homogeneous" systems. A high number of papers describe the preparation of diverse rhodium nanoparticles in suspension for their application as catalysts in hydrogenation of various substrates (mainly olefins and aromatic derivatives) in various catalytic conditions (mainly organic or biphasic phases). Concerning hydroformylation catalysis, it appears that only a few papers deal with rhodium metal nanoparticles for investigation in this reaction, although rhodium is well-known as highly active metal in hydroformylation reaction in homogeneous conditions.
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Dates et versions

hal-00881494 , version 1 (08-11-2013)

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Citer

Miguel Guerrero, Nguyet T. Chau Than, Sébastien Noël, Audrey Denicourt-Nowicki, Frédéric Hapiot, et al.. About the Use of Rhodium Nanoparticles in Hydrogenation and Hydroformylation Reactions. Current Organic Chemistry, 2013, 17 (4), pp.364-399. ⟨10.2174/1385272811317040006⟩. ⟨hal-00881494⟩
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