A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: Liberate H2 from Solar Energy - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Journal of the American Chemical Society Année : 2013

A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: Liberate H2 from Solar Energy

Rajendra S. Dhayal
  • Fonction : Auteur
Jian-Hong Liao
  • Fonction : Auteur
Yan-Ru Lin
  • Fonction : Auteur
Ping-Kuei Liao
  • Fonction : Auteur
Samia Kahlal
  • Fonction : Auteur
  • PersonId : 945136
C.-W. Liu
  • Fonction : Auteur

Résumé

An unprecedented air-stable, nanospheric polyhydrido copper cluster, [Cu20H11(S2P(OiPr)2)9] (1H), which is the first example of an elongated triangular orthobicupola array of Cu atoms having C3h symmetry, was synthesized and characterized. Its composition was primarily determined by electrospray ionization mass spectrometry, and it was fully characterized by 1H, 2H, and 31P NMR spectroscopy and single-crystal X-ray diffraction (XRD). The structure of complex 1H can be expressed in terms of a trigonal-bipyramidal [Cu2H5]3- unit anchored within an elongated triangular orthobicupola containing 18 Cu atoms, which is further stabilized by 18 S atoms from nine dithiophosphate ligands and six capping hydrides. The positions of the 11 hydrides revealed by low temperature XRD were supported by a density functional theory investigation on the simplified model [Cu20H11(S2PH2)9] with C3h symmetry. 1H is capable of releasing H2 gas upon irradiation with sunlight, under mild thermal conditions (65 °C), or in the presence of acids at room temperature.
Fichier non déposé

Dates et versions

hal-00874188 , version 1 (17-10-2013)

Identifiants

Citer

Rajendra S. Dhayal, Jian-Hong Liao, Yan-Ru Lin, Ping-Kuei Liao, Samia Kahlal, et al.. A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: Liberate H2 from Solar Energy. Journal of the American Chemical Society, 2013, 135 (12), pp.4704-4707. ⟨10.1021/ja401576s⟩. ⟨hal-00874188⟩
64 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More