Ruthenium(II) Catalysed Synthesis of Unsaturated Oxazolines via Arene C-H Bond Alkenylation - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Green Chemistry Année : 2012

Ruthenium(II) Catalysed Synthesis of Unsaturated Oxazolines via Arene C-H Bond Alkenylation

Résumé

Monoalkenylation of arene C-H bonds directed by an oxazoline group to afford bifunctional alkenes is described using [RuCl2(p-cymene)]2 as the catalyst in the presence of 1,1′-binaphthyl-2,2′-diyl hydrogenphosphate (BNPAH) and of Cu(OAc)2*H2O under air. This reaction takes place under mild conditions in ethanol at 80 °C and tolerates the oxazoline function.

Domaines

Catalyse
Fichier non déposé

Dates et versions

hal-00872409 , version 1 (12-10-2013)

Identifiants

Citer

Bin Li, Karthik Devaraj, Christophe Darcel, Pierre H. Dixneuf. Ruthenium(II) Catalysed Synthesis of Unsaturated Oxazolines via Arene C-H Bond Alkenylation. Green Chemistry, 2012, 14, pp.2706-2709. ⟨10.1039/C2GC36111F⟩. ⟨hal-00872409⟩
57 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More