Boron- and silicon-substituted [3]-1-heterodendralenes as versatile building blocks for the rapid construction of polycyclic architectures. - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Chemistry - A European Journal Année : 2011

Boron- and silicon-substituted [3]-1-heterodendralenes as versatile building blocks for the rapid construction of polycyclic architectures.

Résumé

B and Si, additional assets: Skeletally diverse polycyclic compounds with up to six stereocenters were assembled with excellent stereoselectivity from simple 2-vinyl α,β-unsaturated aldehydes possessing a trimethylsilyl or a boronate group at position 3 (see scheme). The pre-encoded skeletal information was ensured by the initial choice of the positions of the heteroatoms (O, Si or B).

Dates et versions

hal-00869895 , version 1 (04-10-2013)

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Citer

Fabien Tripoteau, Tristan Verdelet, Alain Hercouet, François Carreaux, Bertrand Carboni. Boron- and silicon-substituted [3]-1-heterodendralenes as versatile building blocks for the rapid construction of polycyclic architectures.. Chemistry - A European Journal, 2011, 17 (49), pp.13670-13675. ⟨10.1002/chem.201101624⟩. ⟨hal-00869895⟩
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