Iridium-Catalyzed Allylic Amination Route to α-Aminoboronates: Illustration of the Decisive Role of Boron Substituents. - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2011

Iridium-Catalyzed Allylic Amination Route to α-Aminoboronates: Illustration of the Decisive Role of Boron Substituents.

Résumé

The development of a new route to α-aminoboronates using an iridium-catalyzed allylic amination on boronated substrates is described. Unlike the boronate group, the trifluoroborato substituent was found to govern the regioselectivity exclusively in favor of branched products. The transformation of an allylic substitution product into an α-aminoboronic ester in an efficient way validated the implementation of this approach.

Domaines

Chimie organique

Dates et versions

hal-00869890 , version 1 (04-10-2013)

Identifiants

Citer

Sabrina Touchet, François Carreaux, Gary A. Molander, Bertrand Carboni, Alexandre Bouillon. Iridium-Catalyzed Allylic Amination Route to α-Aminoboronates: Illustration of the Decisive Role of Boron Substituents.. Advanced Synthesis and Catalysis, 2011, 353 (18), pp.3391-3396. ⟨10.1002/adsc.201100407⟩. ⟨hal-00869890⟩
46 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More