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Article Dans Une Revue Tetrahedron: Asymmetry Année : 2010

Chiral recognition of amines and amino acid derivatives by optically active ruthenium Halterman porphyrins in organic solvents and water

Résumé

The complexation of optically active or racemic amines, amino esters and amino acids with chiral ruthenium Halterman porphyrins is described. For various amino esters, chiral recognition was observed for the complexation of the ligand with up to 60% enantiomeric excess for 1-(1-naphthyl) ethylamine. A water-soluble ruthenium Halterman porphyrin, due to the presence of four sulfonate groups at the para-positions, was also prepared and used for the chiral recognition of amino acids in water.

Domaines

Chimie organique

Dates et versions

hal-00869732 , version 1 (04-10-2013)

Identifiants

Citer

Irène Nicolas, Soizic Chevance, Paul Le Maux, Gérard Simonneaux. Chiral recognition of amines and amino acid derivatives by optically active ruthenium Halterman porphyrins in organic solvents and water. Tetrahedron: Asymmetry, 2010, 21 (13-14), pp.1788-1792. ⟨10.1016/j.tetasy.2010.05.026⟩. ⟨hal-00869732⟩
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