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Article Dans Une Revue Angewandte Chemie International Edition Année : 2010

Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes

Résumé

Reaction of [PdMe2(tmeda)] with pyridyl-N-di(tert-butyl)phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand-based biradical complex, which behaves as a "masked" form of Pd0 in its reactions with neutral ligands and chlorobenzene.

Dates et versions

hal-00860851 , version 1 (11-09-2013)

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Citer

Dan A. Smith, Andrei S. Batsanov, Karine Costuas, Ruth Edge, David C. Apperley, et al.. Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes. Angewandte Chemie International Edition, 2010, 49 (39), pp.7040-7044. ⟨10.1002/anie.201003946⟩. ⟨hal-00860851⟩
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