TRANSDIP: a trans-chelating ligand tailor-made for probing unusual Pd0 and PdII intermediates. - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Chemistry - A European Journal Année : 2012

TRANSDIP: a trans-chelating ligand tailor-made for probing unusual Pd0 and PdII intermediates.

Résumé

Forty years after Venanzi's seminal studies on trans-spanning diphosphines, a cavity-shaped trans chelator (TRANSDIP) has been used to monitor the stepwise formation of a carbon-carbon bond on a palladium centre. Furthermore, the ligand, which incorporates a cyclodextrin subunit, enabled the synthesis of the first η(2)-dioxygen complex in which the M-O(2) unit is entrapped within a cavity.

Dates et versions

hal-00855349 , version 1 (29-08-2013)

Identifiants

Citer

Rafael Gramage-Doria, Dominique Armspach, Dominique Matt, Loïc Toupet. TRANSDIP: a trans-chelating ligand tailor-made for probing unusual Pd0 and PdII intermediates.. Chemistry - A European Journal, 2012, 18 (35), pp.10813-6. ⟨10.1002/chem.201201403⟩. ⟨hal-00855349⟩
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