Mono- and di-cyclocarbonate telechelic polyolefins synthesized from ROMP using glycerol carbonate derivatives as chain-transfer agents - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Polymer Chemistry Année : 2013

Mono- and di-cyclocarbonate telechelic polyolefins synthesized from ROMP using glycerol carbonate derivatives as chain-transfer agents

Résumé

The ring-opening metathesis polymerization (ROMP) of cyclooctene (COE) has been achieved with Grubbs 2nd generation ruthenium catalyst in the presence of vinyl or acryloyl derivatives of glycerol carbonate. Such asymmetric chain-transfer agents enabled the synthesis in high yields of α-cyclocarbonate,ω-vinyl-poly(cyclooctene) (PCOE) and, more rewardingly, of the highly valuable α,ω-dicyclocarbonate telechelic PCOE.

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Dates et versions

hal-00811417 , version 1 (10-04-2013)

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Liana Annunziata, Stéphane Fouquay, Guillaume Michaud, Frederic Simon, Sophie M. Guillaume, et al.. Mono- and di-cyclocarbonate telechelic polyolefins synthesized from ROMP using glycerol carbonate derivatives as chain-transfer agents. Polymer Chemistry, 2013, 4, pp.1313-1316. ⟨10.1039/c2py21141f⟩. ⟨hal-00811417⟩
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