Regio- and stereoselective syntheses of piperidine derivatives via ruthenium-catalyzed coupling of propargylic amides and allylic alcohols. - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2012

Regio- and stereoselective syntheses of piperidine derivatives via ruthenium-catalyzed coupling of propargylic amides and allylic alcohols.

Résumé

Intermolecular selective coupling of linear allylic alcohols and propargylic amides occurs in the presence of a catalytic amount of the cationic ruthenium complex [Cp*Ru(NCCH(3))(3)]PF(6) followed by condensation to generate six-membered cyclic enamides or hemiaminal ethers with water as the only side product.

Domaines

Catalyse
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Dates et versions

hal-00804934 , version 1 (26-03-2013)

Identifiants

Citer

Sathiyamoorthy Murugesan, Fan Jiang, Mathieu Achard, Christian Bruneau, Sylvie Dérien. Regio- and stereoselective syntheses of piperidine derivatives via ruthenium-catalyzed coupling of propargylic amides and allylic alcohols.. Chemical Communications, 2012, 48 (52), pp.6589-91. ⟨10.1039/c2cc32497k⟩. ⟨hal-00804934⟩
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