Bonding and Electronic Structure of Cp*2Ru2(B8H14), a Metalloborane Analogue of Dinuclear Pentalene Complexes - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Journal of Organometallic Chemistry Année : 2012

Bonding and Electronic Structure of Cp*2Ru2(B8H14), a Metalloborane Analogue of Dinuclear Pentalene Complexes

Résumé

DFT calculations were carried out on compound Cp*2Ru2(B8H14) that suggests a strong link with the pentalene complex Cp*2Fe2(C8H6). Both compounds exhibit similar bonding modes and qualitatively related electronic structures. There are however, differences which are related to the weaker B-B bond in the B8H14 ligand as compared to the C-C bond in the pentalene ligand.

Dates et versions

hal-00753608 , version 1 (19-11-2012)

Identifiants

Citer

Benoît Boucher, Sundargopal Ghosh, Jean-François Halet, Samia Kahlal, Jean-Yves Saillard. Bonding and Electronic Structure of Cp*2Ru2(B8H14), a Metalloborane Analogue of Dinuclear Pentalene Complexes. Journal of Organometallic Chemistry, 2012, 721-722, pp.167-172. ⟨10.1016/j.jorganchem.2012.08.033⟩. ⟨hal-00753608⟩
79 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More