Continuous flow homogeneous alkene metathesis with built-in catalyst separation - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Green Chemistry Année : 2011

Continuous flow homogeneous alkene metathesis with built-in catalyst separation

Rubén Duque
  • Fonction : Auteur
Eva Oechsner
  • Fonction : Auteur
Hervé Clavier
Steven P. Nolan
  • Fonction : Auteur
David J. Cole-Hamilton
  • Fonction : Auteur

Résumé

Continuous flow homogeneous alkene metathesis using a supported ionic liquid phase (SILP) catalyst with CO2 as a transport vector allows the self-metathesis of methyl oleate with only a slight loss of activity for at least 10 h; cross-metathesis of dimethyl maleate with methyl oleate ceases after 3 h, but the catalyst remains active for methyl oleate metathesis. The reasons for this unusual behaviour are explored and a practical system for the cross-metathesis of methyl oleate with dimethyl maleate, under batch conditions, is described.

Domaines

Chimie organique
Fichier non déposé

Dates et versions

hal-00753368 , version 1 (19-11-2012)

Identifiants

Citer

Rubén Duque, Eva Oechsner, Hervé Clavier, Frédéric Caijo, Steven P. Nolan, et al.. Continuous flow homogeneous alkene metathesis with built-in catalyst separation. Green Chemistry, 2011, 13, pp.1187-1195. ⟨10.1039/C1GC15048K⟩. ⟨hal-00753368⟩

Relations

107 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More