Investigation of the shape of the R(0) absorption line in ν3, N2O recorded from an axisymmetric supersonic free jet expansion - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Journal of Quantitative Spectroscopy and Radiative Transfer Année : 2007

Investigation of the shape of the R(0) absorption line in ν3, N2O recorded from an axisymmetric supersonic free jet expansion

Résumé

The hydrodynamic structure of an axisymmetric supersonic expansion can be regarded as a series of concentric divergent cones, with decreasing particle densities as the cone angle increases. Different groups of molecules therefore contribute to high-resolution absorption line shapes when optically probing the expansion in a direction perpendicular to the jet axis. These groups are distinguished by the cone angle, inducing a specific Doppler shift, and by the particle density, contributing a specific weight to the absorption intensity. As a result different broader line profiles are observed compared to room temperature spectra. This effect is investigated here selecting as the working example the R(0), ν3 absorption line in N2O recorded using a Fourier transform interferometer. Independent impact pressure and quadrupole mass spectrometric measurements are performed leading to two complementary maps of the expansion, allowing the recorded absorption line shape to be quantitatively modeled.

Dates et versions

hal-00653546 , version 1 (19-12-2011)

Identifiants

Citer

Keevin Didriche, Peter Macko, Michel Herman, Jonathan Thiévin, Abdessamad Benidar, et al.. Investigation of the shape of the R(0) absorption line in ν3, N2O recorded from an axisymmetric supersonic free jet expansion. Journal of Quantitative Spectroscopy and Radiative Transfer, 2007, 105 (1), pp.128-138. ⟨10.1016/j.jqsrt.2006.10.002⟩. ⟨hal-00653546⟩
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