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Article Dans Une Revue Organic Letters Année : 2010

Pyridyldithiafulvenes as precursors of coordination-driven self-assembled redox active macrocycle.

Résumé

A novel redox active macrocycle including two vinylogous tetrathiafulvalenes (TTFVs) and two molybdenum tetracarbonyl fragments has been synthezised thanks to the coordination-driven self-assembly of complementary angular derivatives. Pyridyl vinylogous TTFVs have been deliberately elaborated for that purpose, using the oxidative coupling of pyridyldithiafulvenes (DTF). Cyclic voltammetry, IR and NMR spectroscopies, and single-crystal X-ray crystallography of the target molecules have been investigated.

Domaines

Chimie organique
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Dates et versions

hal-00502147 , version 1 (13-07-2010)

Identifiants

Citer

Elodie Gontier, Nathalie Bellec, Pierre Brignou, Arnaud Gohier, Thierry Roisnel, et al.. Pyridyldithiafulvenes as precursors of coordination-driven self-assembled redox active macrocycle.. Organic Letters, 2010, 12 (10), pp.2386-9. ⟨10.1021/ol1007422⟩. ⟨hal-00502147⟩
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