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Article Dans Une Revue Journal of Cluster Science Année : 2009

Cations insertion in molybdenum cluster compounds: electronic structure and electrochemical study using cavity microelectrode

Résumé

Owing to the high lability of cations in the three-dimensional framework of K1+x Mo12S14 (0 ≤ x ≤ 1.6), first-principles calculations and electrochemical methods have been carried out to study the insertion of cations in the empty channels of this compound. The cavity microelectrode that is a suitable electrode for powder material analysis has been used in voltammetric experiments. Results obtained for Li+, Na+, Rb+, K+, Cs+ and NH4 + cations are presented and discussed.

Dates et versions

hal-00414528 , version 1 (09-09-2009)

Identifiants

Citer

Sofiane Bouazza, Diala Salloum, Régis Gautier, Patrick Gougeon, Michel Potel, et al.. Cations insertion in molybdenum cluster compounds: electronic structure and electrochemical study using cavity microelectrode. Journal of Cluster Science, 2009, 20 (1), pp.133-143. ⟨10.1007/s10876-008-0211-8⟩. ⟨hal-00414528⟩
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