Synthesis crystal structures and magnetic properties of 2,3,6,7-Tetrakis(2-cyanoethylthio)tetrathiafulvalene polymers - UFR SPM Sciences et Propriétés de la Matière
Article Dans Une Revue AIP Conference Proceedings Année : 2024

Synthesis crystal structures and magnetic properties of 2,3,6,7-Tetrakis(2-cyanoethylthio)tetrathiafulvalene polymers

Résumé

The detailed synthesis, crystal structures and magnetic properties of several transition metal complexes involving oxidized or neutral 2,3,6,7-Tetrakis(2-cyanoethylthio) tetrathiafulvalene (TCE-TTF) are presented. All compounds revealed polymeric arrangements with metal ions bridging TCE-TTF with Metal-Nitrogen bounds. Strong van-der-Waals interactions between polymers increased the dimensionality of the materials. The magnetic behaviour of hetero-bimetallic compound [M(1)$^{II}$(TCE-TTF$^{●+}$)$_2$M(2)$^{II}$(H$_2$O)$_4$](ClO$_4$)$_6$•2H$_2$O with M = Zn/Mn is also studied.
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Dates et versions

hal-04689860 , version 1 (06-09-2024)

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Stéphane Golhen, Jean Olivier, Olivier Cador, Lahcène Ouahab. Synthesis crystal structures and magnetic properties of 2,3,6,7-Tetrakis(2-cyanoethylthio)tetrathiafulvalene polymers. AIP Conference Proceedings, 2024, 3068 (1), pp.020001. ⟨10.1063/5.0202562⟩. ⟨hal-04689860⟩
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