Metal-to-metal electron transfer in a cyanido-bridged {Fe<sub>2</sub>Co<sub>2</sub>} square complex followed by X-ray diffraction and absorption techniques - Equipe de Recherche en Matériaux Moléculaires et Spectroscopies
Article Dans Une Revue Chemical Communications Année : 2022

Metal-to-metal electron transfer in a cyanido-bridged {Fe2Co2} square complex followed by X-ray diffraction and absorption techniques

Dmitri Mitcov
Loic Toupet
Elzbieta Trzop
Eric Collet

Résumé

The switching properties of a cyanido-bridged Fe/Co square molecule were investigated by single-crystal X-ray diffraction and X-ray absorption spectroscopy at both Fe and Co K-edges. Combining these two techniques, a complete picture of the thermal-, light-and X-rayinduced metal-to-metal electron transfer is obtained, illustrating the concerted role played by the Fe and Co sites.
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Dates et versions

hal-03821953 , version 1 (20-10-2022)

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Corine Mathonière, Dmitri Mitcov, Evangelia Koumousi, Daniel Amorin-Rosario, Pierre Dechambenoit, et al.. Metal-to-metal electron transfer in a cyanido-bridged {Fe2Co2} square complex followed by X-ray diffraction and absorption techniques. Chemical Communications, 2022, 58 (86), pp.12098-12101. ⟨10.1039/d2cc04246k⟩. ⟨hal-03821953⟩
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